On the question of steric repulsion versus noncovalent attractive interactions in chiral phosphoric acid catalyzed asymmetric reactions-Reference-Cited by-同舟云学术

On the question of steric repulsion versus noncovalent attractive interactions in chiral phosphoric acid catalyzed asymmetric reactions

Published:2021 Issue:34 Volume:23 Page:18936-18950
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Tribedi Soumi¹^ORCID,Kitaura Kazuo²³,Nakajima Takahito²^ORCID,Sunoj Raghavan B.¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India

2. RIKEN Center for Computational Science, 7-1-26 Minatojima-minami-machi, Chuo-ku, Kobe, Hyogo 650-0047, Japan

3. Fukui Institute for Fundamental Chemistry, Kyoto University, Takano-Nishihiraki-cho 34-4, Sakyou-ku, Kyoto 606-8103, Japan

Abstract

The balance between attractive noncovalent interactions and the repulsive steric interaction is quantified in the enantiocontrolling transition states in chiral phosphoric acid catalyzed asymmetric transformations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP02499J

Reference61 articles.

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3. Noncovalent Interactions in Organocatalysis and the Prospect of Computational Catalyst Design

4. Transition State Models for Understanding the Origin of Chiral Induction in Asymmetric Catalysis

5. Harnessing weak interactions for enantioselective catalysis

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