Accumulation of counterions and coions evaluated by cryogenic XPS as a new tool for describing the structure of electric double layer at the silica/water interface

Author:

Škvarla Jiří1234ORCID,Kaňuchová Mária1234,Shchukarev Andrey5678,Brezáni Ivan1234,Škvarla Juraj9101112

Affiliation:

1. Institute of Earth Resources

2. Technical University in Košice

3. 042 00 Košice

4. Slovak Republic

5. Department of Chemistry

6. Umeå University

7. S-901 87 Umeå

8. Sweden

9. Department of Physical and Macromolecular Chemistry

10. Charles University in Prague

11. 128 40 Prague 2

12. Czech Republic

Abstract

We introduce a new method of evaluating the structure of electric double layer (EDL) at the native solid/liquid interface using cryogenic X-ray photoelectron spectroscopy technique.

Funder

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference44 articles.

1. The Electrical Double Layer. A general Discussion of the Faraday Society (1939–1940), Gurney and Jackson, 1940, p. 732

2. M. J. Sparnay , The Electrical Double Layer, Pergamon Press, Oxford, 1972, p. 415

3. Electrical Double Layers in Biology, ed. M. Blank, Plenum Press, New York, 1986, p. 319

4. H. Ohshima , Theory of Colloid and Interfacial Electric Phenomena, Elsevier, Amsterdam, 2006, p. 473

5. S. Durand-Vidal , J.-P.Simonin and P.Turq, Electrolytes at Interfaces, Kluwer Academic Press, Dordrecht, 2000, p. 344

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