Biomimetic flavin-catalysed reactions for organic synthesis

Author:

Iida H.12345,Imada Y.6785,Murahashi S.-I.19105

Affiliation:

1. Department of Chemistry

2. Interdisciplinary Graduate School of Science and Engineering

3. Shimane University

4. Matsue 690-8504

5. Japan

6. Department of Chemical Science and Technology

7. Tokushima University

8. Tokushima 770-8506

9. Okayama University of Science

10. Okayama 700-0005

Abstract

Using simple riboflavin related compounds as biomimetic catalysts, catalytic oxidation of various substrates with hydrogen peroxide or molecular oxygen can be performed selectively under mild conditions. The principle of these reactions is fundamental and will provide a wide scope for environmentally benign future practical methods.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference100 articles.

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2. Modern Oxidation Methods, ed. J.-E. Bäckvall, Wiley-VCH, Weinheim, 2nd edn, 2010

3. Synthetic Aspects of Metal-Catalyzed Oxidations of Amines and Related Reactions

4. B. Meunier , Biomimetic Oxidations Catalyzed by Transition Metal Complexes, Imperial College Press, London, 2000

5. Ruthenium catalyzed biomimetic oxidation in organic synthesis inspired by cytochrome P-450

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