Electrochemical remote C(sp<sup>3</sup>)–H thiocyanation-Reference-Cited by-同舟云学术

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Electrochemical remote C(sp³)–H thiocyanation

Published:2024 Issue:8 Volume:11 Page:2283-2288
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Pang Xinyu¹,He Hui²,Meng Xiangrui¹,Zhang Linbao¹^ORCID,Ni Shaofei²,Li Ming¹,Guo Weisi¹^ORCID

Affiliation:

1. College of Chemistry & Molecular Engineering, Qingdao University of Science & Technology, 53 Zhengzhou Road, Qingdao, P. R. China

2. Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong, Shantou University, Shantou 515063, Guangdong, P. R. China

Abstract

An electrochemical thiocyanation of distal C(sp3)–H bonds based on amidyl radical-mediated 1,5-HAT has been developed. The transformation is highly site-selective and compatible with primary, secondary, and tertiary sulfonamides, and bioactive derivatives.

Funder

Natural Science Foundation of Shandong Province

Science and Technology Support Plan for Youth Innovation of Colleges and Universities of Shandong Province of China

Shantou University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00032C

Reference53 articles.

1. When Light Meets Nitrogen-Centered Radicals: From Reagents to Catalysts

2. New amination strategies based on nitrogen-centered radical chemistry

3. Recent progress in the generation and use of nitrogen-centred radicals

4. Ueber die Einwirkung des Broms in alkalischer Lösung auf die Amine

5. An Iodine-Catalyzed Hofmann-Löffler Reaction

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