Manganese-catalyzed transfer semihydrogenation of internal alkynes to <i>E</i>-alkenes with iPrOH as hydrogen source-Reference-Cited by-同舟云学术

Manganese-catalyzed transfer semihydrogenation of internal alkynes to E-alkenes with iPrOH as hydrogen source

Published:2022 Issue:9 Volume:12 Page:3004-3015
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Torres-Calis Antonio¹^ORCID,García Juventino J.¹^ORCID

Affiliation:

1. Facultad de Química, Universidad Nacional Autónoma de México, Mexico City, 04510, Mexico

Abstract

The Mn-catalyzed transfer semihydrogenation of internal alkynes to E-alkenes is reported herein, along with Mn-catalyzed hydration of α-keto alkynes. Mechanistic studies displayed an asymmetrical Mn-hydride species performing the catalytic turnover.

Funder

Consejo Nacional de Ciencia y Tecnología

Dirección General de Asuntos del Personal Académico, Universidad Nacional Autónoma de México

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D2CY00246A

Reference104 articles.

1. The Golden Age of Transfer Hydrogenation

2. Catalytic asymmetric transfer hydrogenation of ketones: recent advances