Pyridine imines as ligands in luminescent iridium complexes
Author:
Affiliation:
1. Department of Chemistry
2. University of Leicester
3. Leicester LE1 7RH, UK
4. La.M.I. and LaSCAMM
5. INSTM Sezione Basilicata
6. Dipartimento di Scienze
7. Università della Basilicata
8. 85100 Potenza, Italy
Abstract
Biscyclometallated iridium complexes [Ir(ppz)2(X^Y)][PF6] (X^Y = pyridine imine) have been synthesised; N-alkyl complexes are emissive whilst N-aryl ones are only weakly emissive, DFT calculations shed light on the reasons for this difference.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT52975D
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