Energy partitioning and spin–orbit effects in the photodissociation of higher chloroalkanes-Reference-Cited by-同舟云学术

Energy partitioning and spin–orbit effects in the photodissociation of higher chloroalkanes

Published:2021 Issue:26 Volume:23 Page:14340-14351
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Vinklárek Ivo S.¹²³^ORCID,Suchan Jiří⁴³^ORCID,Rakovský Jozef¹²³^ORCID,Moriová Kamila¹²³^ORCID,Poterya Viktoriya¹²³^ORCID,Slavíček Petr⁴³^ORCID,Fárník Michal¹²³^ORCID

Affiliation:

1. J. Heyrovský Institute of Physical Chemistry, v.v.i.

2. The Czech Academy of Sciences

3. Czech Republic

4. University of Chemistry and Technology

Abstract

Photodissociation of the C–Cl bond in chloroalkanes probed by ab initio simulations and velocity map imaging identify the alkyl chain as a soft energy absorbing unit and an increasing role of spin–orbit coupling with the alkyl chain prolongation.

Funder

Ministerstvo Školství, Mládeže a Tělovýchovy

Grantová Agentura České Republiky

Grantová Agentura, Univerzita Karlova

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP01371H

Reference72 articles.

1. Excited fragments from excited molecules: energy partitioning in the photodissociation of alkyl iodides

2. Two‐dimensional imaging of state‐selected photodissociation products detected by multiphoton ionization

3. Photodissociation of molecular beams of halogenated hydrocarbons at 193 nm

4. Diode laser spectroscopy for monitoring the yield of metastable Cl from photodissociation of simple molecules

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. On the Wavelength-Dependent Photochemistry of the Atmospheric Molecule CF₃COCl;ACS Earth and Space Chemistry;2023-10-16

2. Optimization of the femtosecond laser impulse for excitation and the Spin-Orbit mediated dissociation in the NaRb Dimer;Journal of Quantitative Spectroscopy and Radiative Transfer;2023-09