Polarization-dependent effects in vibrational absorption spectra of 2D finite-size adsorbate islands on dielectric substrates

Author:

Zerulla Benedikt1ORCID,Krstić Marjan2ORCID,Chen Shuang3,Yu Zairan3,Beutel Dominik2ORCID,Holzer Christof2ORCID,Nyman Markus1ORCID,Nefedov Alexei3ORCID,Wang Yuemin3ORCID,Mayerhöfer Thomas G.4ORCID,Wöll Christof3ORCID,Rockstuhl Carsten12ORCID

Affiliation:

1. Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Kaiserstr. 12, 76131 Karlsruhe, Germany

2. Institute of Theoretical Solid State Physics, Karlsruhe Institute of Technology (KIT), Kaiserstr. 12, 76131 Karlsruhe, Germany

3. Institute of Functional Interfaces, Karlsruhe Institute of Technology (KIT), Kaiserstr. 12, 76131 Karlsruhe, Germany

4. Leibniz Institute of Photonic Technology, Albert-Einstein-Str. 9, 07745 Jena, Germany

Abstract

In this article, we analyze polarization-dependent effects in vibrational absorption spectra of 2D finite-size adsorbate islands on dielectric substrates. Using a multi-scale approach, we predict the transition from finite-size islands to a monolayer.

Funder

Bundesministerium für Bildung und Forschung

Carl-Zeiss-Stiftung

Karlsruhe Institute of Technology

Helmholtz-Gemeinschaft

Deutsche Forschungsgemeinschaft

Volkswagen Foundation

Helmholtz Association

Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg

Publisher

Royal Society of Chemistry (RSC)

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