Manganese catalysed reduction of nitriles with amine boranes

Author:

Weber Stefan1ORCID,Blaha Ines1,Kirchner Karl1ORCID

Affiliation:

1. Institute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163-AC, A-1060 Wien, Austria

Abstract

The room temperature reduction of various nitriles using amine boranes catalysed by a manganese(i) alkyl complex is described. Based on experimental findings, a plausible mechanistic scenario is presented.

Funder

Austrian Science Fund

Publisher

Royal Society of Chemistry (RSC)

Reference47 articles.

1. H.-U.Blaser , F.Spindler and M.Thommen , in The Handbook of Homogeneous Hydrogenation , ed. J. G. de Vries and C. J. Elsevier , Wiley-VCH , Weinheim , 2008 , ch. 37, pp. 1279–1324

2. P. N.Rylander , Best Synthetic Methods: Hydrogenation Methods , Academic Press , Orlando. Florida , 1985 , ch. 3, pp. 53–65

3. The Golden Age of Transfer Hydrogenation

4. Synthesis of ammonia borane for hydrogen storage applications

5. A review on the catalysts used for hydrogen production from ammonia borane

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