On the urea induced hydrophobic collapse of a water soluble polymer
Author:
Affiliation:
1. Eduard-Zintl-Institut für Anorganische und Physikalische Chemie and Center of Smart Interfaces
2. Technische Universität Darmstadt
3. Darmstadt
4. Germany
Abstract
Polymer collapse despite cosolvent binding: solvation of extended coil conformations is entropically penalized, therefore stabilizing compact globular conformations in the coil-globule equilibrium of poly(N-isopropylacrylamide) in aqueous urea solution.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP05314A
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