B-embedded disulfide-bridged π-conjugated compounds: structures and optical tuning

Author:

Ye Kaishun1,Li Gang12,Li Feiyang1ORCID,Shi Chao1ORCID,Jiang Zhen1,Zhang Fuzheng1,Li Qiuxia1,Su Jie1,Song Dandan34ORCID,Yuan Aihua1ORCID

Affiliation:

1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China

2. CSMC Technologies Fab2 Co., Ltd, Wuxi, 214028, China

3. Key Laboratory of Luminescence and Optical Information (Beijing Jiaotong University), Ministry of Education, Beijing 100044, China

4. Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China

Abstract

Two novel B-embedded disulfide-bridged π-conjugated compounds have been prepared and show different optical mechanisms. The compound BS-CZ exhibits significant MR-TADF properties, while the compound BS-N shows traditional FL characteristics.

Funder

National Natural Science Foundation of China

Postdoctoral Research Foundation of China

Natural Science Foundation of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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