Decomposition of methanol-d4 on Rh nanoclusters supported by thin-film Al2O3/NiAl(100) under near-ambient-pressure conditions-Reference-Cited by-同舟云学术

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Decomposition of methanol-d₄ on Rh nanoclusters supported by thin-film Al₂O₃/NiAl(100) under near-ambient-pressure conditions

Published:2024 Issue:6 Volume:26 Page:5059-5069
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Liao Guan-Jr¹,Hsueh Wen-Hao²^ORCID,Yen Yu-Hsiang¹,Shih Yi-Chan¹,Wang Chia-Hsin³,Wang Jeng-Han²,Luo Meng-Fan¹^ORCID

Affiliation:

1. Department of Physics, National Central University, No. 300 Jhongda Road, Jhongli 32054, Taiwan

2. Department of Chemistry, National Taiwan Normal University, No. 88, Section 4, Ting-Zhou Road, Taipei, Taiwan

3. National Synchrotron Radiation Research Center, 101 Hsin-Ann Road, Hsinchu Science Park, Hsinchu 30076, Taiwan

Abstract

A NAP size effect on methanol-d4 decomposition on supported Rh nanoclusters was investigated and found to involve co-adsorbed water (H2O*) and its dissociation (into OH*) dependent on the cluster size.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D3CP05303B

Reference69 articles.

1. Ultrathin metal films and particles on oxide surfaces: structural, electronic and chemisorptive properties

2. Surface studies of supported model catalysts

3. Metal clusters on ultrathin oxide films: model catalysts for surface science studies

4. Metal deposits on well-ordered oxide films

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