Highly enantioselective construction of tertiary thioethers and alcohols via phosphine-catalyzed asymmetric γ-addition reactions of 5H-thiazol-4-ones and 5H-oxazol-4-ones: scope and mechanistic understandings-Reference-Cited by-同舟云学术

Highly enantioselective construction of tertiary thioethers and alcohols via phosphine-catalyzed asymmetric γ-addition reactions of 5H-thiazol-4-ones and 5H-oxazol-4-ones: scope and mechanistic understandings

Published:2015 Issue:8 Volume:6 Page:4912-4922
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang Tianli¹²³⁴,Yu Zhaoyuan⁵⁶⁷⁸,Hoon Ding Long¹²³⁴,Huang Kuo-Wei⁹¹⁰¹¹¹²¹³,Lan Yu⁵⁶⁷⁸,Lu Yixin¹²³⁴

Affiliation:

1. Department of Chemistry

2. National University of Singapore

3. Singapore 117543

4. Singapore

5. School of Chemistry and Chemical Engineering

6. Chongqing University

7. Chongqing 400030

8. P. R. China

9. Division of Physical Sciences and Engineering

10. KAUST Catalysis Center

11. King Abdullah University of Science and Technology

12. Thuwal 23955-6900

13. Saudi Arabia

Abstract

A new method for facile access to enantioenriched tertiary thioethers/alcohols.

Funder

National University of Singapore

Ministry of Education - Singapore

GlaxoSmithKline

Economic Development Board - Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01614B

Reference149 articles.

1. A. Thuillier and P.Metzner, Sulfur Reagents in Organic Synthesis, ed. A. R. Katritzky, O. Meth-Cohn and C. S. Rees, Academic Press, 1995

2. Organosulfur Chemistry in Asymmetric Synthesis, ed. T. Toru and C. Bolm, Wiley-VCH, Weinheim, 2008

3. C. Chatgilialoglu and K.-D.Asmus, Sulfur-Centered Reactive Intermediates in Chemistry and Biology, Springer, 1991

4. J. M. Berg , J. L.Tymoczko and L.Stryer, Biochemistry, Freeman, 5th edn, 2002

5. Thiols in Cellular Redox Signalling and Control

Cited by 124 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Regioselectivity Switch of α-Amino Acid-Derived Esters and MBH Carbonates for the Synthesis of Allyl-Substituted Azlactones;The Journal of Organic Chemistry;2024-02-28

2. Advances in Organocatalytic Asymmetric Reactions Involving Thioesters;Acta Chimica Sinica;2023

3. Organocatalytic Enantioselective Mannich-type Addition of 5H-Oxazol-4-ones to Isatin Derived Ketimines;CHEM J CHINESE U;2022

4. Phosphine-catalyzed divergent domino processes between γ-substituted allenoates and carbonyl-activated alkenes;Chemical Science;2022

5. [3 + 2] vs. [4 + 1] Annulation: revisiting mechanism studies on the phosphine-catalysed domino sequence of alkynoates and activated methylenes;Organic & Biomolecular Chemistry;2022