Performance of enhanced DuBois type water reduction catalysts (WRC) in artificial photosynthesis – effects of various proton relays during catalysis

Author:

Viertl Wolfgang12345,Pann Johann12345,Pehn Richard12345,Roithmeyer Helena12345,Bendig Marvin12345,Rodríguez-Villalón Alba678,Bereiter Raphael12345,Heiderscheid Max12345,Müller Thomas12345,Zhao Xia91011,Hofer Thomas S.12345ORCID,Thompson Mark E.12131415ORCID,Shi Shuyang12131415,Brueggeller Peter12345ORCID

Affiliation:

1. University of Innsbruck

2. Centrum for Chemistry and Biomedicine

3. Institute of General, Inorganic and Theoretical Chemistry

4. 6020 Innsbruck

5. Austria

6. Complutense University of Madrid

7. 28040 Madrid

8. Spain

9. Northwest University

10. Xi’an 710069

11. P. R. China

12. University of Southern California

13. Irani Chair of Chemistry Department of Chemistry, Chemical Engineering and Materials Science

14. Los Angeles

15. USA

Abstract

A pincer type ligand provides an additional coordination site or a proton relay depending on the metal oxidation state.

Funder

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Reference67 articles.

1. R. K. Pachauri and L. A.Meyer , Climate Change 2014: Synthesis Report. Fifth Assessment Report , IPCC , Geneva, Switzerland , 2014

2. J. D. Sutter and J.Berlinger , Final draft of climate deal formally accepted in Paris , 2015

3. Cobalt and nickel diimine-dioxime complexes as molecular electrocatalysts for hydrogen evolution with low overvoltages

4. Phosphine Coordination to a Cobalt Diimine–Dioxime Catalyst Increases Stability during Light-Driven H2 Production

5. Molecular engineering of a cobalt-based electrocatalytic nanomaterial for H2 evolution under fully aqueous conditions

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