Palladium/copper-cocatalyzed three-component tandem cyclization of <i>o</i>-alkenyl arylisocyanides and sulfur ylides with alcohols: direct synthesis of spiro 3,3′-cyclopropyl oxindoles-Reference-Cited by-同舟云学术

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Palladium/copper-cocatalyzed three-component tandem cyclization of o-alkenyl arylisocyanides and sulfur ylides with alcohols: direct synthesis of spiro 3,3′-cyclopropyl oxindoles

Published:2024 Issue:12 Volume:11 Page:3369-3375
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Gong Yue¹,Xu Xue-Cen¹,Yang Zi-Xuan¹,Zhao Yu-Long¹^ORCID

Affiliation:

1. Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China

Abstract

A novel palladium/copper-cocatalyzed tandem cyclization of o-alkenyl arylisocyanides and sulfur ylides with alcohols has been developed, providing a simple and efficient method for the synthesis of spiro 3,3′-cyclopropyl oxindoles in a single step.

Funder

Natural Science Foundation of Jilin Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00560K

Reference60 articles.

1. Recent advances in the total synthesis of cyclopropane-containing natural products

2. Isatins As Privileged Molecules in Design and Synthesis of Spiro-Fused Cyclic Frameworks

3. A Copper-Catalyzed Aerobic Cascade Dehydrogenative- Dehalogenative Reaction

4. Recent advances in spirocyclization of indole derivatives

5. A new vinyl selenone-based domino approach to spirocyclopropyl oxindoles endowed with anti-HIV RT activity

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