The sol–gel autocombustion as a route towards highly CO2-selective, active and long-term stable Cu/ZrO2 methanol steam reforming catalysts

Author:

Ploner Kevin1,Delir Kheyrollahi Nezhad Parastoo1,Gili Albert23ORCID,Kamutzki Franz2,Gurlo Aleksander2,Doran Andrew4ORCID,Cao Pengfei5,Heggen Marc5,Köwitsch Nicolas6ORCID,Armbrüster Marc6,Watschinger Maximilian1,Klötzer Bernhard1,Penner Simon1ORCID

Affiliation:

1. Department of Physical Chemistry, University of Innsbruck, Innrain 52c, A-6020 Innsbruck, Austria

2. Chair of Advanced Ceramic Materials, Institut für Werkstoffwissenschaften und -technologien, Technical University Berlin, Hardenbergstr. 40, D-10623 Berlin, Germany

3. Institute of Chemistry, Technical University Berlin, Sekretariat TC 8, Straße des 17. Juni 124, D-10623 Berlin, Germany

4. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California, 94720, USA

5. Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons, Forschungszentrum Jülich GmbH, Leo-Brandt-Str. 1, D-52428 Jülich, Germany

6. Faculty of Natural Sciences, Institute of Chemistry, Materials for Innovative Energy Concepts, Technical University Chemnitz, Straße der Nationen 62, D-09111 Chemnitz, Germany

Abstract

The adaption of the sol–gel autocombustion method to the Cu/ZrO2 system opens new pathways for the specific optimisation of the activity, long-term stability and CO2 selectivity of methanol steam reforming (MSR) catalysts.

Funder

Austrian Science Fund

Deutsche Forschungsgemeinschaft

Universität Innsbruck

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Materials Science

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