Interactions and reactivity in crystalline intermediates of mechanochemical cyclorhodation reactions

Author:

Gómez Sara1ORCID,Gómez Santiago2ORCID,Rojas-Valencia Natalia2ORCID,Hernández José G.2ORCID,Ardila-Fierro Karen J.2ORCID,Gómez Tatiana3ORCID,Cárdenas Carlos45,Hadad Cacier2ORCID,Cappelli Chiara1ORCID,Restrepo Albeiro2ORCID

Affiliation:

1. Scuola Normale Superiore, Classe di Scienze, Piazza dei Cavalieri 7, 56126, Pisa, Italy

2. Instituto de Química, Universidad de Antioquia UdeA, Calle 70 No. 52–21, Medellín, Colombia

3. Theoretical and Computational Chemistry Center, Institute of Applied Chemical Sciences, Faculty of Engineering, Universidad Autonoma de Chile, Avenida Pedro de Valdivia 425, Santiago, Chile

4. Departamento de Física, Facultad de Ciencias, Universidad de Chile, Casilla 653, Santiago, Chile

5. Centro para el desarrollo de las Nanociencias y Nanotecnología, CEDENNA, Av. Ecuador 3493, Santiago, Chile

Abstract

State of the art computations help explain the differences in reactivity between transient cocrystals that precede the mechanochemical activation of C–H bonds during the formation of rhodacyles.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Universidad de Antioquia

Centro para el Desarrollo de la Nanociencia y la Nanotecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Calcium Carbide (CaC2) as a C2‐Synthon by Mechanochemistry;ChemPlusChem;2024-07-22

2. Intermediates in Mechanochemical Reactions;Angewandte Chemie International Edition;2024-01-24

3. Intermediates in Mechanochemical Reactions;Angewandte Chemie;2024-01-24

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