Copolymerization of propylene with styrene and ethylene by a THF-containing half-sandwich scandium catalyst: efficient synthesis of polyolefins with a controllable styrene content-Reference-Cited by-同舟云学术

Copolymerization of propylene with styrene and ethylene by a THF-containing half-sandwich scandium catalyst: efficient synthesis of polyolefins with a controllable styrene content

Published:2017 Issue:3 Volume:8 Page:615-623
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Tan Rui¹²³⁴⁵,Guo Fang¹²³⁴⁵,Li Yang¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Fine Chemicals

2. School of Chemical Engineering

3. Dalian University of Technology

4. Dalian 116024

5. China

Abstract

A novel family of multi-block propylene–styrene copolymers with syndiotactic styrene–styrene blocks and random propylene–ethylene–styrene terpolymers with a broad composition range were obtained by using (C₅Me₄SiMe₃)Sc(CH₂SiMe₃)₂(THF).

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2017/PY/C6PY01665K

Reference74 articles.

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4. Ethylene/propylene copolymerization catalyzed by vanadium complexes containing N-heterocyclic carbenes

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