Visible-light-promotedE-selective synthesis of α-fluoro-β-arylalkenyl sulfidesviathe deoxygenation/isomerization process-Reference-Cited by-同舟云学术

Visible-light-promotedE-selective synthesis of α-fluoro-β-arylalkenyl sulfidesviathe deoxygenation/isomerization process

Published:2021 Issue:17 Volume:57 Page:2152-2155
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Li Yuxiu¹²³⁴^ORCID,Li Xiangqian¹²³⁴,Li Xiaowei¹²³⁴,Shi Dayong¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Microbial Technology, and Marine Biotechnology Research Center

2. Shandong University

3. Qingdao 266237

4. P. R. China

5. Laboratory for Marine Biology and Biotechnology

Abstract

HighlyE-selective synthesis of α-fluoro-β-arylalkenyl sulfides: regioselective synthesis of α-fluoro-β-arylalkenyl sulfides has been established withgem-difluoroalkenes and sodium arysulfinatesviavisible-light-induced deoxygenation of S–O bonds and isomerization of alkenes. Moreover, the strategy is also applied in the late-stage modification of complex natural products and drugs.

Funder

Fundamental Research Fund of Shandong University

China Postdoctoral Science Foundation

Natural Science Foundation of Shandong Province

National Program for Support of Top-notch Young Professionals

Taishan Scholar Project of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D0CC08254F

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