Synthesis and characterization of bis(imino)pyridine complexes of divalent Mg and Zn
Author:
Affiliation:
1. Department of Chemistry
2. University of California
3. Davis
4. USA
Abstract
The synthesis and electronic structure of bis(imino)pyridine (I2P) complexes of the divalent metal ions, Zn(ii) and Mg(ii) are reported, and a correlation between the ligand Cim–Cpy bond lengths with the ligand torsion angle is described. Structural comparison with a new complex of Al(iii) and previously reported Al(iii) complexes is included.
Funder
Division of Chemistry
Alfred P. Sloan Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT01541C
Reference39 articles.
1. Bis(imino)pyridines: Surprisingly Reactive Ligands and a Gateway to New Families of Catalysts
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4. Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes
5. Countercations Direct One- or Two-Electron Oxidation of an Al(III) Complex and Al(III)–Oxo Intermediates Activate C–H Bonds
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