Influence of redox initiator component ratios on the emulsion copolymerisation of vinyl acetate and neodecanoic acid vinyl ester-Reference-Cited by-同舟云学术

Influence of redox initiator component ratios on the emulsion copolymerisation of vinyl acetate and neodecanoic acid vinyl ester

Published:2022 Issue:22 Volume:12 Page:14197-14208
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Jacob Laurence Isabelle¹,Pauer Werner¹^ORCID,Schroeter Baldur²^ORCID

Affiliation:

1. Institute for Technical and Macromolecular Chemistry, University of Hamburg, Bundesstraße 45, 20146 Hamburg, Germany

2. Institute of Thermal Separation Processes, Hamburg University of Technology, Eißendorfer Straße 38, 21073 Hamburg, Germany

Abstract

Reaction rate control and high conversions at all temperatures were achieved in emulsion copolymerisation of vinyl acetate and Versa®10 by variation of redox initiator component ratios in a broad range of initiation temperatures of −1 °C to 60 °C.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D2RA01811J

Reference53 articles.

1. Organometallic-Mediated Alternating Radical Copolymerization of tert -Butyl-2-Trifluoromethacrylate with Vinyl Acetate and Synthesis of Block Copolymers Thereof

2. Nitroxide-Mediated Alternating Copolymerization of Vinyl Acetate with tert-Butyl-2-trifluoromethacrylate Using a SG1-Based Alkoxyamine

3. Block Copolymerization of Vinyl Acetate and Vinyl neo-Decanoate Mediated by Dithionodisulfide

4. Facile synthesis of branched polyvinyl acetate via redox-initiated radical polymerization

5. Organometallic-mediated radical polymerization of ‘less activated monomers’: Fundamentals, challenges and opportunities

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