Theoretical investigations of the Ir-catalyzed direct borylation of B(3,6)–H of o-carborane: the actual catalyst, mechanism, and origin of regioselectivity-Reference-Cited by-同舟云学术

Theoretical investigations of the Ir-catalyzed direct borylation of B(3,6)–H of o-carborane: the actual catalyst, mechanism, and origin of regioselectivity

Published:2018 Issue:20 Volume:8 Page:5165-5177
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Bai Huining¹²³⁴,Xu Hao¹²³⁴,Zhang Huimin¹²³⁴,Guo Yuen¹²³⁴,Shan Jiankai¹²³⁴,Wei Donghui¹²³⁴^ORCID,Zhu Yanyan¹²³⁴,Zhang Shouren⁵⁶⁷³⁸,Zhang Wenjing¹²³⁴^ORCID

Affiliation:

1. College of Chemistry and Molecular Engineering

2. Zhengzhou University

3. Zhengzhou

4. P. R. China

5. Henan Provincial Key Laboratory of Nanocomposites and Applications

6. Institute of Nanostructured Functional Materials

7. Huanghe Science and Technology College

8. China

Abstract

The Ir^III species is proved to be the actual catalyst. The electron-delocalized structure and the inductive effects of the carbon centers is account for the regioselectivity.

Funder

China Postdoctoral Science Foundation

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY01322E

Reference94 articles.

1. R. N. Grimes , Carboranes , 2nd edn, 2011

2. N. S. Hosmane , Boron Science: New Technologies and Applications , CRC Press , 2011