cis- and trans-Dichloro-derivatives of six- and seven-co-ordinate zirconium and hafnium bonded to quadridentate Schiff-base ligands. Crystal structures of [Zr(acen)Cl2(thf)], [M(salphen)Cl2(thf)]·0.5thf, [M(acen)Cl2], (M = Zr or Hf), and [Zr(msal)Cl2][acen =N,N′-ethylenebis(acetylacetoneiminate), salphen =N,N′-o-phenylenebis(salicylideneiminate), msal =N-methylsalicylideneiminate, and thf = tetrahydrofuran]-Reference-Cited by-同舟云学术

cis- and trans-Dichloro-derivatives of six- and seven-co-ordinate zirconium and hafnium bonded to quadridentate Schiff-base ligands. Crystal structures of [Zr(acen)Cl2(thf)], [M(salphen)Cl2(thf)]·0.5thf, [M(acen)Cl2], (M = Zr or Hf), and [Zr(msal)Cl2][acen =N,N′-ethylenebis(acetylacetoneiminate), salphen =N,N′-o-phenylenebis(salicylideneiminate), msal =N-methylsalicylideneiminate, and thf = tetrahydrofuran]

Published:1990 Issue:4 Volume: Page:1335-1344
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Corazza Fabio,Solari Euro,Floriani Carlo,Chiesi-Villa Angiola,Guastini Carlo

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1990/DT/DT9900001335

Reference33 articles.

1. M. Bottrill , P. D.Gavens, and J.McMeeking, in ‘Comprehensive Organometallic Chemistry,’ eds. G. Wilkinson, F. G. A. Stone, and E. W. Abel, Pergamon, Oxford, 1982, vol. 3, ch. 22.2, p. 281;

2. M. Bottrill , P. D.Gavens, and J.McMeeking, in ‘Comprehensive Organometallic Chemistry,’ eds. G. Wilkinson, F. G. A. Stone, and E. W. Abel, Pergamon, Oxford, 1982, vol. 3, ch. 22.3, p. 232;

3. D. J. Cardin , M. F.Lappert, C. L.Raston, and P. I.Riley, in ‘Comprehensive Organometallic Chemistry,’ eds. G. Wilkinson, F. G. A. Stone, and E. W. Abel, Pergamon, Oxford, 1982, vol. 3, ch. 23.2, p. 559.

4. Organotitanium reagents in organic synthesis a simple means to adjust reactivity and selectivity of carbanions

5. Reactivity of dioxygen with group 4A alkoxy alkyls: epoxidation via metal alkyl mediated oxygen atom transfer

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