Octahedral alkylidyne complexes of tungsten with chelating ligands as precursors for polynuclear compounds. Crystal structures of [W(CR)(CO)2(dmpe)(NCS)] and [Co2W(µ3-CR)(CO)8(dmpe)Br](R = C6H4Me-4, dmpe = Me2PCH2CH2PMe2)-Reference-Cited by-同舟云学术

Octahedral alkylidyne complexes of tungsten with chelating ligands as precursors for polynuclear compounds. Crystal structures of [W(CR)(CO)2(dmpe)(NCS)] and [Co2W(µ3-CR)(CO)8(dmpe)Br](R = C6H4Me-4, dmpe = Me2PCH2CH2PMe2)

Published:1990 Issue:11 Volume: Page:3355-3362
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Carriedo Gabino A.,Sánchez Gema,Riera Victor,Bois Claudette,Jeannin Yves,Miguel Daniel

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1990/DT/DT9900003355

Reference22 articles.

1. Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 92. Synthesis of alkynylmethylidyne-molybdenum and -tungsten complexes and their reactions with [Co2(CO)8] and [Mo2(CO)6(η-C5H5)2]

2. Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 87. Docosahedral carbaborane(alkylidyne)tungsten complexes as reagents for the synthesis of compounds with heteronuclear metal–metal bonds: crystal structures of [NEt4][W(CC6H6Me2-2,6)(CO)2(η6-C2B10H10Me2)] and [NEt4][WFe(µ-CC6H3Me2-2,6)(CO)4(η6-C2B10H10Me2)]

3. Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 88. Carbaboranetungsteniridium compounds; crystal structure of the complex [WIr(µ-CC6H4Me-4)(CO)2(PEt3)2(η5-C2B9H9Me2)]

4. Chemistry of di- and tri-metal complexes with bridging carbene or carbyne ligands. Part 3. Synthesis of bimetallic platinum–tungsten complexes with µ-tolylidyne groups; crystal structure of [PtW(µ-C·C6H4Me-p)(CO)2(PMe2Ph)2(η-C5H5)]

5. Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 72. Di- and tri-metal compounds prepared from the alkylidyne tungsten complexes [W(CR)(CO)3{H2B(pz)2}][R = C6H4Me-4 or Me, H2B(pz)2= dihydrobis(pyrazol-1-yl)borate]

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