A theoretical investigation of substituent effects on the stability and reactivity of N-heterocyclic olefin carboxylates
Author:
Affiliation:
1. Institute of Nuclear Physics and Chemistry
2. China Academy of Engineering Physics
3. Mianyang
4. P. R. China
5. School of Science
6. Xihua University
7. Chengdu
Abstract
Introduction of four phenyl groups at C-position and N-position not only favors decarboxylation but also ensures NHO as a strong nucleophile.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB01021G
Reference77 articles.
1. Sustainable conversion of carbon dioxide: the advent of organocatalysis
2. Recent developments in carbon dioxide utilization for the production of organic chemicals
3. Recent developments in carbon dioxide utilization under mild conditions
4. Chemistry of Carbon Dioxide Relevant to Its Utilization: A Personal Perspective
5. Recent Advances in Carbon Dioxide Capture, Fixation, and Activation by using N-Heterocyclic Carbenes
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