Base induced C–CN bond cleavage at room temperature: a convenient method for the activation of acetonitrile
Author:
Affiliation:
1. Sate Key Laboratory of Structural Chemistry
2. Fujian Institute of Research on the Structure of Matter
3. Chinese Academy of Sciences
4. Fuzhou
5. China
Abstract
Acetonitrile was activated to form formaldehyde and cyanide in air. Utilization of the product [CuII–CN] for catalytic cyanation was investigated.
Funder
National Natural Science Foundation of China
Chinese Academy of Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/QI/C8QI01258J
Reference49 articles.
1. Transition metal-catalyzed carbon–carbon bond activation
2. Metal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent Recovery
3. Direct Approaches to Nitriles via Highly Efficient Nitrogenation Strategy through C–H or C–C Bond Cleavage
4. Catalytic reactions involving the cleavage of carbon–cyano and carbon–carbon triple bonds
5. Recent Advances in Transition-Metal-Catalyzed Functionalization of Unstrained Carbon–Carbon Bonds
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