Homoallyl alcohol as an allylation reagent for termination of the Catellani–Lautens reaction <i>via</i> retro-allylation-Reference-Cited by-同舟云学术

Homoallyl alcohol as an allylation reagent for termination of the Catellani–Lautens reaction via retro-allylation

Published:2023 Issue:4 Volume:10 Page:898-904
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Du Xueyan¹,Yang Xiaozhe¹,Wang Han¹,Li Xinguang¹,Wang Murong¹,Li Xiang¹,Tao Ye²,Yang Yaxing²,Tan Xinqiang¹,Ren Feng¹³,Zhou Ping-Xin¹^ORCID,Liang Yong-Min⁴^ORCID

Affiliation:

1. School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang, China

2. Department of Biochemistry, University of Texas Southwestern Medical Center, Dallas, USA

3. Henan International Joint Laboratory of Immunity and Targeted Therapy for liver-intestinal Tumors, Xinxiang Medical University, Xinxiang, China

4. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, China

Abstract

A palladium/norbornene-catalyzed ortho-amination/allylation of aryl iodides was developed for the construction of ortho-aminated allylbenzene by using N-benzoyloxyamine as the amination reagent and homoallyl alcohol as the allylation reagent.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D2QO01609E

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