Stepwise reduction of a corannulene-based helical molecular nanographene with Na metal-Reference-Cited by-同舟云学术

Stepwise reduction of a corannulene-based helical molecular nanographene with Na metal

Published:2022 Issue:37 Volume:58 Page:5574-5577
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhou Zheng¹²^ORCID,Zhu Yikun¹^ORCID,Fernández-García Jesús M.³^ORCID,Wei Zheng¹^ORCID,Fernández Israel³^ORCID,Petrukhina Marina A.¹^ORCID,Martín Nazario³⁴^ORCID

Affiliation:

1. Department of Chemistry, University at Albany, State University of New York Albany, NY 12222, USA

2. School of Materials Science and Engineering, Tongji University, 4800 Cao’an Road, Shanghai 201804, China

3. Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Ciudad Universitaria s/n, 28040 Madrid, Spain

4. IMDEA-Nanociencia, C/Faraday, 9, Campus de Cantoblanco, 28049 Madrid, Spain

Abstract

The two-electron stepwise reduction of a corannulene-based nanographene (C76H64) with Na metal leads to an aromaticity change (from aromatic to non-aromatic or antiaromatic) observed on the most affected rings, which is fully reversible.

Funder

Ministerio de Ciencia e Innovación

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC00971D

Reference56 articles.

1. C60: Buckminsterfullerene

2. M. A.Petrukhina and L. T.Scott , Fragments of Fullerenes and Carbon Nanotubes: Designed Synthesis, Unusual Reactions, and Coordination Chemistry , John Wiley & Sons, Inc. , Hoboken, NJ , 2012

3. Understanding the reactivity of polycyclic aromatic hydrocarbons and related compounds

4. Corannulene: A Curved Polyarene Building Block for the Construction of Functional Materials

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