The influence of sample mass (scaling effect) on the synthesis and structure of non-graphitizing carbon (biochar) during the analytical pyrolysis of biomass

Author:

Nair Rahul Ramesh1ORCID,Kißling Patrick A.2,Schaate Andreas34ORCID,Marchanka Alexander5ORCID,Shamsuyeva Madina6,Behrens Peter37ORCID,Weichgrebe Dirk1

Affiliation:

1. Institute of Sanitary Engineering and Waste Management (ISAH), Leibniz University of Hannover, Hannover, 30167, Germany

2. Institute of Physical Chemistry and Electrochemistry (PCI), Leibniz University of Hannover, Hannover, 30167, Germany

3. Institute of Inorganic Chemistry (ACI), Leibniz University of Hannover, Hannover, 30167, Germany

4. Laboratory of Nano and Quantum Engineering, Leibniz University of Hannover, Hannover, 30167, Germany

5. Institute of Organic Chemistry and Centre of Biomolecular Drug Research (BMWZ), Leibniz University of Hannover, Hannover, 30167, Germany

6. Institute of Plastics and Circular Economy (IKK), Leibniz University of Hannover, Garbsen, 30823, Germany

7. Cluster of Excellence PhoenixD (Photonics, Optics, and Engineering – Innovation Across Disciplines), Leibniz University of Hannover, Hannover, 30167, Germany

Abstract

The sample mass during biomass pyrolysis in an thermogravimetric reactor is shown to influence the pyrolysis mechanism and properties of the resultant non-graphitizing carbon. There is an inflection mass scale beyond which this effect is minimal.

Funder

Gottfried Wilhelm Leibniz Universität Hannover

Deutscher Akademischer Austauschdienst

Bundesministerium für Bildung und Forschung

Indo-German Science and Technology Centre

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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