Palladium-catalyzed ortho-acyloxylation of N-nitrosoanilines via direct sp2 C–H bond activation-Reference-Cited by-同舟云学术

Palladium-catalyzed ortho-acyloxylation of N-nitrosoanilines via direct sp2 C–H bond activation

Published:2015 Issue:25 Volume:13 Page:6958-6964
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Li Dan-Dan¹²³⁴⁵,Cao Yi-Xuan¹²³⁴⁵,Wang Guan-Wu¹²³⁴⁵

Affiliation:

1. Hefei National Laboratory for Physical Sciences at Microscale

2. iChEM (Collaborative Innovation Center of Chemistry for Energy Materials)

3. and Department of Chemistry

4. University of Science and Technology of China

5. Hefei

Abstract

The palladium-catalyzed N-nitroso-directed ortho-acyloxylation of N-nitrosoanilines has been demonstrated via sp² C–H activation with PhI(OAc)₂ as the oxidant and Ac₂O/AcOH (1 : 1) or C₂H₅CO₂H as the reaction medium.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB00691K

Reference79 articles.

1. Carbon–hydrogen (C–H) bond activation at PdIV: a Frontier in C–H functionalization catalysis

2. Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

3. Towards mild metal-catalyzed C–H bond activation

4. Challenge and progress: palladium-catalyzed sp3 C–H activation

5. Palladium-catalysed hydroxylation and alkoxylation

Cited by 48 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Parallel Synthesis of Pyrazolone-Fused Cinnolines by the Palladium-Catalyzed [4 + 2] Annulation of Pyrazol-3-ones with Substituted Allenoates;The Journal of Organic Chemistry;2023-12-22

2. Recent Advances in Functionalization of Aromatic C(sp²)—H Bonds Based on N-Nitroso Direction;Chinese Journal of Organic Chemistry;2023

3. Denitrosation of Aryl-N-nitrosamines by a Transnitrosation Strategy Using Ethanethiol and p-Toluenesulfonic Acid under Mild Reaction Conditions;Synlett;2022-12-11

4. A study of the reactivity and transformations of Pd/NHC complexes in the reaction of oxidative C−H acetoxylation;Russian Chemical Bulletin;2022-06

5. Directed aromatic C–H functionalization of N-arylcarbamates and quinazolinones catalyzed by palladium nanoparticles supported on nitrogen-doped graphene;Colloid and Interface Science Communications;2022-03