Transition-state scaling relations in zeolite catalysis: influence of framework topology and acid-site reactivity-Reference-Cited by-同舟云学术

Transition-state scaling relations in zeolite catalysis: influence of framework topology and acid-site reactivity

Published:2015 Issue:5 Volume:5 Page:2814-2820
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Wang Chuan-Ming¹²³⁴⁵,Brogaard Rasmus Y.⁴⁵⁶⁷⁸,Xie Zai-Ku¹²³,Studt Felix⁴⁵⁶⁷⁸

Affiliation:

1. SINOPEC Shanghai Research Institute of Petrochemical Technology

2. Shanghai 201208

3. China

4. SUNCAT Center for Interface Science and Catalysis

5. SLAC National Accelerator Laboratory

6. USA

7. Department of Chemical Engineering

8. Stanford University

Abstract

Transition-state enthalpies in olefin–methanol reactions scale linearly with ammonia adsorption enthalpy as descriptor of acid site reactivity in zeolite catalysis. The slopes of these scaling relations vary with dispersion interaction with the framework.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CY/C4CY01692K

Reference65 articles.

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2. Impact of Zeolites on the Petroleum and Petrochemical Industry

3. Hydrocarbons from Methanol

4. Methanol-to-hydrocarbons: catalytic materials and their behavior

5. Reactivity Theory of Zeolitic Broensted Acidic Sites

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