17O NMR and15N NMR chemical shifts of sterically-hindered amides: ground-state destabilization in amide electrophilicity-Reference-Cited by-同舟云学术

17O NMR and15N NMR chemical shifts of sterically-hindered amides: ground-state destabilization in amide electrophilicity

Published:2019 Issue:30 Volume:55 Page:4423-4426
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Pace Vittorio¹²³⁴⁵^ORCID,Holzer Wolfgang¹²³⁴⁵^ORCID,Ielo Laura¹²³⁴⁵,Shi Shicheng⁶⁷⁸⁹^ORCID,Meng Guangrong⁶⁷⁸⁹^ORCID,Hanna Mina⁶⁷⁸⁹,Szostak Roman⁶¹⁰¹¹¹²^ORCID,Szostak Michal¹³¹⁴¹⁵¹⁶⁶^ORCID

Affiliation:

1. Department of Pharmaceutical Chemistry

2. Faculty of Life Sciences

3. University of Vienna

4. Vienna A-1090

5. Austria

6. Department of Chemistry

7. Rutgers University

8. Newark

9. USA

10. Wroclaw University

11. Wroclaw 50-383

12. Poland

13. College of Chemistry and Chemical Engineering and Key Laboratory of Auxiliary Chemistry and Technology for Chemical Industry

14. Ministry of Education

15. Xi'an 710021

16. China

Abstract

We report¹⁷O NMR and¹⁵N NMR spectroscopic data for sterically-hindered acyclic amides. The data demonstrate that a combined use of¹⁷O NMR and¹⁵N NMR serves as a powerful tool in assessing electronic effects of the amide bond.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC01402K

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