Mechanism of methylphosphonic acid photo-degradation based on phosphate oxygen isotopes and density functional theory

Author:

Xia Congcong12345,Geng Huanhuan4563,Li Xiaobao123,Zhang Yiyue4563,Wang Fei4563ORCID,Tang Xiaowen7893,Blake R. E.456310,Li Hui10111213,Chang Sae Jung10111213,Yu Chan4563

Affiliation:

1. Jiangxi Transportation Institute China

2. 330038 Nanchang

3. China

4. School of Energy & Environmental Engineering

5. University of Science and Technology Beijing

6. 100083 Beijing

7. School of Pharmaceutical Sciences

8. Sun Yet-sen University

9. 510006 Guangzhou

10. Department of Geology and Geophysics

11. Yale University

12. New Haven

13. USA

Abstract

Methylphosphonic acid (MPn) is an intermediate in the synthesis of the phosphorus-containing nerve agents, such as sarin and VX, and a biosynthesis product of marine microbes with ramifications to global climate change and eutrophication.

Funder

National Natural Science Foundation of China

National Aeronautics and Space Administration

National Science Foundation

Natural Science Foundation of Beijing Municipality

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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