Tuning the supramolecular isomerism of MOF-74 by controlling the synthesis conditions

Author:

Gheorghe Andreea1ORCID,Imaz Inhar2,van der Vlugt Jarl Ivar3ORCID,Maspoch Daniel24ORCID,Tanase Stefania1ORCID

Affiliation:

1. Heterogeneous Catalysis and Sustainable Chemistry, Van‘t Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam, The Netherlands

2. Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and Barcelona Institute of Science and Technology, Campus UAB, Bellaterra 08193, Barcelona, Spain

3. Bioinspired, Homogeneous & Supramolecular Catalysis, Van‘t Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands

4. ICREA, Pg. Lluís Companys 23, 08010 Barcelona, Spain

Abstract

Controlled synthesis of MOF materials with specific properties is highly relevant for practical applications and it still remains a challenging task. This work highlights the key role played by the solvents and specific modulators in the formation and stability of two isomers of the well-known MOF-74.

Funder

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Ministerio de Economía y Competitividad

Agència de Gestió d’Ajuts Universitaris i de Recerca

H2020 European Research Council

Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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