Facile construction of dibenzodioxo[3.3.1]nonanes bearing spirocyclohexadienones <i>via</i> domino [4 + 2] cycloaddition/C(sp<sup>3</sup>)–H oxidative dehydrogenation coupling reactions-Reference-Cited by-同舟云学术

Facile construction of dibenzodioxo[3.3.1]nonanes bearing spirocyclohexadienones via domino [4 + 2] cycloaddition/C(sp³)–H oxidative dehydrogenation coupling reactions

Published:2022 Issue:47 Volume:20 Page:9392-9396
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Chen Genhui¹,Li Hongjiao¹,Liang Guojuan¹,Pu Qian¹,Bai Lijuan¹,Zhang Dexin¹,Ye Ying¹,Li Yong²,Zhou Jing¹^ORCID,Zhou Hui¹^ORCID

Affiliation:

1. Chongqing Research Center for Pharmaceutical Engineering, College of Pharmacy, Chongqing Medical University, Chongqing 400016, China

2. College of Pharmacy, National & Local Joint Engineering Research Center of Targeted and Innovative Therapeutics, IATTI, Chongqing University of Arts and Sciences, Chongqing 402160, China

Abstract

A novel palladium catalyzed domino [4 + 2] cycloaddition/C(sp3)–H oxidative dehydrogenation coupling reaction was developed. An interesting palladium catalyzed benzyl C–H oxidation dehydrogenation to form a transannular C(sp3)–O bond was found.

Funder

Science and Technology Planning Project of Yuzhong District of Chongqing City

Chongqing Medical University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB01860H

Reference32 articles.

1. Four new flavonoids from the leaves of Morus mongolica

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