Synergy of metallic Pt and oxygen vacancy sites in Pt–WO<sub>3−<i>x</i></sub> catalysts for efficiently promoting vanillin hydrodeoxygenation to methylcyclohexane-Reference-Cited by-同舟云学术

Synergy of metallic Pt and oxygen vacancy sites in Pt–WO_3−x catalysts for efficiently promoting vanillin hydrodeoxygenation to methylcyclohexane

Published:2022 Issue:24 Volume:24 Page:9489-9495
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Sun Mengya¹²,Zhang Yanfei¹²,Liu Wang¹²,Zhao Xinpeng¹²,Luo Hu¹,Miao Gai¹,Wang Zhiqiang³,Li Shenggang¹²⁴^ORCID,Kong Lingzhao¹²⁵^ORCID

Affiliation:

1. CAS Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, PR China

2. University of Chinese Academy of Sciences, Beijing 100049, PR China

3. Department of Coal and Syngas Conversion, Sinopec Research Institute of Petroleum Processing, Beijing, 100083, PR China

4. School of Physical Science and Technology, Shanghai-Tech University, Shanghai, 200031, PR China

5. School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou, Jiangsu, 215009, PR China

Abstract

Pt–WO3−x catalysts with more Pt0 species and proximity of oxygen vacancy active sites derived from WO3−x, assisted by the hydrogen spillover effect, lead to an excellent methylcyclohexane yield (92.5%) at 220 °C, under 4.0 MPa H2 in n-hexane solvent.

Funder

Ministry of Science and Technology of the People's Republic of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/GC/D2GC03144B

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