Mechanical generation of isocyanate by mechanically induced retro [2 + 2] cycloaddition of a 1,2-diazetidinone mechanophore
Author:
Affiliation:
1. Department of Chemistry
2. Duke University
3. Durham
4. USA
Abstract
Mechanical activation of a 1,2-diazetidinone mechanophore via ultrasonic sonication leads to the formation of isocyanate and imine products.
Funder
Division of Chemistry
Duke University
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00262F
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1. Editing of polymer backbones;Nature Reviews Chemistry;2023-08-04
2. Synthesis of Nβ-Substituted 1,2-Diazetidin-3-ones by the Ugi Reaction Comprising Chiral α-Hydrazino Acids;The Journal of Organic Chemistry;2022-05-13
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