Magnetic exchange, anisotropy and excitonic fluctuations in a [NiII7] Anderson wheel-Reference-Cited by-同舟云学术

Magnetic exchange, anisotropy and excitonic fluctuations in a [NiII7] Anderson wheel

Published:2024 Issue:2 Volume:11 Page:515-525
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Payne Emily H.¹^ORCID,Wilson Lucinda R. B.¹^ORCID,Singh Mukesh K.¹^ORCID,Nichol Gary S.¹^ORCID,Stewart J. R.²,Garcia-Sakai V.²^ORCID,Ewings R. A.²,Lane Harry³,Schnack Jürgen⁴^ORCID,Stock Chris³,Brechin Euan K.¹^ORCID

Affiliation:

1. EaStCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, Edinburgh, EH9 3FJ, Scotland, UK

2. ISIS Pulsed Neutron and Muon Source, STF Rutherford Appleton Laboratory, Harwell Campus, Didcot, Oxon, OX11 0QX, UK

3. School of Physics and Astronomy, The University of Edinburgh, Edinburgh, EH9 3JZ, Scotland, UK

4. Fakultät für Physik, Universität Bielefeld, Postfach 100131, D-33501 Bielefeld, Germany

Abstract

Susceptibility and magnetisation measurements, magnetic neutron spectroscopy and first principles calculations reveal the presence of competing ferro- and antiferromagnetic exchange interactions and both easy plane and easy axis anisotropy in a [Ni7] Anderson wheel.

Funder

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QI/D3QI02307A

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