High capacity ammonia adsorption in a robust metal–organic framework mediated by reversible host–guest interactions

Author:

Guo Lixia1ORCID,Han Xue1ORCID,Ma Yujie1ORCID,Li Jiangnan1ORCID,Lu Wanpeng1ORCID,Li Weiyao1ORCID,Lee Daniel2ORCID,da Silva Ivan3ORCID,Cheng Yongqiang4,Rudić Svemir3ORCID,Manuel Pascal3,Frogley Mark D.5ORCID,Ramirez-Cuesta Anibal J.4ORCID,Schröder Martin1ORCID,Yang Sihai1ORCID

Affiliation:

1. Department of Chemistry, University of Manchester, Manchester, M13 9PL, UK

2. Department of Chemical Engineering and Analytical Science, University of Manchester, Manchester, M13 9PL, UK

3. ISIS Facility, STFC Rutherford Appleton Laboratory, Oxfordshire, OX11 0QX, UK

4. Neutron Scattering Division, Neutron Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA

5. Diamond Light Source, Harwell Science and Innovation Campus, Oxfordshire, OX11 0DE, UK

Abstract

To understand the exceptional adsorption of NH3 in MFM-300(Sc), we report a full study of the mechanism of adsorption by in situ neutron diffraction, inelastic neutron scattering, synchrotron infrared microspectroscopy, and 45Sc NMR spectroscopy.

Funder

Engineering and Physical Sciences Research Council

H2020 European Research Council

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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