Building a robust 3D Ca-MOF by a new square Ca4O SBU for purification of natural gas-Reference-Cited by-同舟云学术

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Building a robust 3D Ca-MOF by a new square Ca4O SBU for purification of natural gas

Published:2020 Issue:26 Volume:49 Page:8836-8840
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hu Falu¹²³⁴⁵,Di Zhengyi⁶⁷⁸⁹⁴,Wu Mingyan⁶⁷⁸⁹⁴,Li Jing¹²³⁴⁵^ORCID

Affiliation:

1. Hoffmann Institute of Advanced Materials

2. Shenzhen Polytechnic

3. Shenzhen

4. China

5. Department of Chemistry and Chemical Biology

6. State Key Laboratory of Structure Chemistry

7. Fujian Institute of Research on the Structure of Matter

8. Chinese Academy of Sciences

9. Fuzhou

Abstract

For the first time, a new square Ca₄O SBU is introduced into a 3D Ca-MOF, ([MeNH₂]₂[Ca₄O(MTB)₂(EtOH)₄])·(solvent)n (1), to generate a structure with (4,8)-connected flu-topology, which shows good selectivity of CO₂, C₂ and C₃ hydrocarbons over CH₄.

Funder

Shenzhen Polytechnic

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00943A

Reference80 articles.

1. Metal–organic framework materials as catalysts

2. Modular Metal–Organic Polyhedra Superassembly: From Molecular‐Level Design to Targeted Drug Delivery

3. Selective gas adsorption and separation in metal–organic frameworks

4. Role of Hydrogen Bonding on Transport of Coadsorbed Gases in Metal–Organic Frameworks Materials

5. Metal–Organic Framework Materials for the Separation and Purification of Light Hydrocarbons

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