Unravelling the role of active-site isolation in reactivity and reaction pathway control for acetylene hydrogenation-Reference-Cited by-同舟云学术

Unravelling the role of active-site isolation in reactivity and reaction pathway control for acetylene hydrogenation

Published:2020 Issue:47 Volume:56 Page:6372-6375
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Liu Siyang¹²³⁴⁵,Niu Yiming⁶⁷⁸⁹⁵,Wang Yongzhao⁶⁷⁸⁹⁵,Chen Junnan⁶⁷⁸⁹⁵,Quan Xueping⁶⁷⁸⁹⁵,Zhang Xia¹²³⁴⁵^ORCID,Zhang Bingsen⁶⁷⁸⁹⁵^ORCID

Affiliation:

1. Department of Chemistry

2. College of Science

3. Northeastern University

4. Shenyang 110819

5. China

6. Shenyang National Laboratory for Materials Science

7. Institute of Metal Research

8. Chinese Academy of Sciences

9. Shenyang 110016

Abstract

Supported Pd_xCu_y bimetallic catalysts were prepared and characterized to illustrate the active-site isolation effect on controlling the reactivity and reaction pathway of acetylene hydrogenation.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC01889A

Reference30 articles.

1. Microporous metal–organic framework with dual functionalities for highly efficient removal of acetylene from ethylene/acetylene mixtures

2. Improved selectivity of carbon-supported palladium catalysts for the hydrogenation of acetylene in excess ethylene

3. Highly efficient and selective catalytic hydrogenation of acetylene in N,N-dimethylformamide at room temperature

4. Selective Hydrogenation of Ethyne in Ethene‐Rich Streams on Palladium Catalysts. Part 1. Effect of Changes to the Catalyst During Reaction

5. Selective Hydrogenation of Ethyne in Ethene‐Rich Streams on Palladium Catalysts, Part 2: Steady‐State Kinetics and Effects of Palladium Particle Size, Carbon Monoxide, and Promoters

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