Directed nucleophilic addition of phenoxides to cyclopropenes-Reference-Cited by-同舟云学术

Directed nucleophilic addition of phenoxides to cyclopropenes

Published:2017 Issue:38 Volume:15 Page:8153-8165
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Yamanushkin Pavel¹²³⁴,Lu-Diaz Michael¹²³⁴¹,Edwards Andrew¹²³⁴,Aksenov Nicolai A.¹⁵⁶⁷,Rubina Marina¹²³⁴⁸,Rubin Michael¹²³⁴¹^ORCID

Affiliation:

1. Department of Chemistry

2. University of Kansas

3. Lawrence

4. USA

5. North Caucasus Federal University

6. Stavropol 355009

7. Russian Federation

8. Peoples’ Friendship University of Russia

Abstract

The alkali metal-templated addition of aryloxides across the double bond of non-conjugated cyclopropenes is described. High cis-selectivity is achieved through a directing effect of a strategically positioned carboxamide functionality.

Funder

Russian Foundation for Basic Research

Ministry of Education and Science of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB01785E

Reference57 articles.

1. Catalytic Enantioselective Hydrostannation of Cyclopropenes

2. A New Chiral Rh(II) Catalyst for Enantioselective [2 + 1]-Cycloaddition. Mechanistic Implications and Applications

3. Copper-Catalyzed Diastereo- and Enantioselective Desymmetrization of Cyclopropenes: Synthesis of Cyclopropylboronates

4. Catalytic Enantioselective Hydroboration of Cyclopropenes

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