Tuning rare-earth hydride reactivity with a reductive diazabutadienyl ligand beyond insertion-Reference-Cited by-同舟云学术

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Tuning rare-earth hydride reactivity with a reductive diazabutadienyl ligand beyond insertion

Published:2024 Issue:13 Volume:11 Page:3799-3810
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Lin Xiaoqing¹,Zhang Jie¹^ORCID,Zhou Xigeng¹^ORCID

Affiliation:

1. Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, People's Republic of China

Abstract

An unusual hydrogen radical addition and SET process between one H- and two DAD’ ligands has been observed in the reaction of 2 with PhCCH.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QI/D4QI00412D

Reference95 articles.

1. Organolanthanide and organoyttrium hydride chemistry. 5. Improved synthesis of [(C5H4R)2YH(THF)]2 complexes and their reactivity with alkenes, alkynes, 1,2-propadiene, nitriles, and pyridine, including structural characterization of an alkylideneamido product

2. Synthesis, Structure, and Reactions of Hydride, Borohydride, and Aluminohydride Compounds of the f-Elements

3. Non-metallocene hydride complexes of the rare-earth metals

4. Molecular Rare-Earth-Metal Hydrides in Non-Cyclopentadienyl Environments

5. Cationic rare-earth metal hydrides

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