Palladium-catalyzed denitrogenative cycloadditions and alkenylations of benzotriazoles with alkynes
Author:
Affiliation:
1. School of Pharmaceutical Sciences
2. MOE Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology
3. Tsinghua University
4. Beijing 100084
5. China
Abstract
Palladium-catalyzed denitrogenative cycloadditions and alkenylations of benzotriazoles with alkynes have been achieved under different conditions, which enable the divergent syntheses of three types of valuable scaffolds.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Beijing Municipality
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00778K
Reference55 articles.
1. Palladium-Catalyzed Indolization of N-Aroylbenzotriazoles with Disubstituted Alkynes
2. Diverse Visible‐Light‐Promoted Functionalizations of Benzotriazoles Inspired by Mechanism‐Based Luminescence Screening
3. Regioselective Synthesis of 2-Substituted Indoles from Benzotriazoles and Alkynes by Photoinitiated Denitrogenation
4. Denitrogenative Suzuki and carbonylative Suzuki coupling reactions of benzotriazoles with boronic acids
5. Palladium-catalyzed denitrogenative functionalizations of benzotriazoles with alkenes and 1,3-dienes
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