Thermal synthesis of electron deficient oxygen species on crystalline IrO2

Author:

Carbonio E. A.12ORCID,Sulzmann F.2,Teschner D.23,Velasco-Vélez J. J.234,Hävecker M.13,Gericke A. Knop23,Schlögl R.123,Jones T.25

Affiliation:

1. Catalysts for Energy, Energy Materials In-situ Laboratory (EMIL), Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, BESSY II, Albert-Einstein-Straße 15, 12489 Berlin, Germany

2. Department of Inorganic Chemistry, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany

3. Department of Heterogeneous Reactions, Max Planck Institute for Chemical Energy Conversion, Stiftstraße 34-36, Mülheim an der Ruhr 45470, Germany

4. ALBA Synchrotron Light Source, Cerdanyola del Vallés (Barcelona) 08290, Spain

5. Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

Abstract

μ2-O species shown to be active in OER can be thermally produced on crystalline IrO2 bound to IrIV+δ without requiring the presence of IrIII, which offers a route to higher-performance stable OER catalysts.

Funder

Los Alamos National Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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