Self-complementary nickel halides enable multifaceted comparisons of intermolecular halogen bonds: fluoride ligands vs. other halides

Author:

Thangavadivale Vargini1234,Aguiar Pedro M.12345ORCID,Jasim Naseralla A.1234,Pike Sarah J.1234ORCID,Smith Dan A.1234,Whitwood Adrian C.1234ORCID,Brammer Lee1674ORCID,Perutz Robin N.1234ORCID

Affiliation:

1. Department of Chemistry

2. University of York

3. York YO10 5DD

4. UK

5. Département de Chimie

6. University of Sheffield

7. Sheffield S3 7HF

Abstract

Studies of X–Ni–C6F4I⋯X–Ni–C6F4I halogen-bonded networks reveal pronounced differences between fluoride (X = F) and other halides: the 19F-MAS NMR spectrum is a sensitive probe of the halogen bond.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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