Self-complementary nickel halides enable multifaceted comparisons of intermolecular halogen bonds: fluoride ligands vs. other halides
Author:
Affiliation:
1. Department of Chemistry
2. University of York
3. York YO10 5DD
4. UK
5. Département de Chimie
6. University of Sheffield
7. Sheffield S3 7HF
Abstract
Studies of X–Ni–C6F4I⋯X–Ni–C6F4I halogen-bonded networks reveal pronounced differences between fluoride (X = F) and other halides: the 19F-MAS NMR spectrum is a sensitive probe of the halogen bond.
Funder
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC00890F
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