Observation of electrochemically generated nitrenium ions by desorption electrospray ionization mass spectrometry
Author:
Affiliation:
1. Department of Chemistry
2. Stanford University
3. Stanford
4. USA
5. Center for Intelligent Chemical Instrumentation
6. Department of Chemistry and Biochemistry and Edison Biotechnology Institute
7. Ohio University
8. Athens
Abstract
Electrochemically generated nitrenium ions from amines can be detected mass spectrometrically using desorption electrospray ionization on a rotating conducting wheel covered with an electrolyte film.
Funder
Division of Chemistry
Air Force Office of Scientific Research
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC02939B
Reference34 articles.
1. D. E. Falvey , in Reactive Intermediate Chemistry, ed. R. A. Moss, M. S. Platz and M. Jones Jr, John Wiley & Sons, Inc., 2003, pp. 593–650
2. Nitrenium ions
3. Nitrenium ions: structure and reactivity
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