Observation of electrochemically generated nitrenium ions by desorption electrospray ionization mass spectrometry

Author:

Brown Timothy A.1234,Hosseini-Nassab Niloufar1234,Chen Hao56784,Zare Richard N.1234

Affiliation:

1. Department of Chemistry

2. Stanford University

3. Stanford

4. USA

5. Center for Intelligent Chemical Instrumentation

6. Department of Chemistry and Biochemistry and Edison Biotechnology Institute

7. Ohio University

8. Athens

Abstract

Electrochemically generated nitrenium ions from amines can be detected mass spectrometrically using desorption electrospray ionization on a rotating conducting wheel covered with an electrolyte film.

Funder

Division of Chemistry

Air Force Office of Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference34 articles.

1. D. E. Falvey , in Reactive Intermediate Chemistry, ed. R. A. Moss, M. S. Platz and M. Jones Jr, John Wiley & Sons, Inc., 2003, pp. 593–650

2. Nitrenium ions

3. Nitrenium ions: structure and reactivity

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