Unravelling free volume in branched-cation ionic liquids based on silicon-Reference-Cited by-同舟云学术

Unravelling free volume in branched-cation ionic liquids based on silicon

Published:2022 Issue:31 Volume:13 Page:9062-9073
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Bakis Eduards¹^ORCID,Goloviznina Kateryna²^ORCID,Vaz Inês C. M.²^ORCID,Sloboda Diana¹,Hazens Daniels¹,Valkovska Valda¹,Klimenkovs Igors¹^ORCID,Padua Agilio²^ORCID,Costa Gomes Margarida²^ORCID

Affiliation:

1. Faculty of Chemistry, University of Latvia, Jelgavas 1, Riga, LV-1004, Latvia

2. Laboratoire de Chimie, ENS de Lyon and CNRS, 46 Allée D’Italie, Lyon 69364, France

Abstract

The branching of ionic liquid cation sidechains utilizing silicon as the backbone was explored and it was found that this structural feature leads to fluids with remarkably low density and viscosity.

Funder

Latvijas Zinātnes Padome

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC01696F

Reference46 articles.

1. Free Volume as the Basis of Gas Solubility and Selectivity in Imidazolium-Based Ionic Liquids

2. Assessing the Dispersive and Electrostatic Components of the Cohesive Energy of Ionic Liquids Using Molecular Dynamics Simulations and Molar Refraction Data

3. Fluorinated Ionic Liquids: Properties and Applications