“C–H⋯π Interaction” regulates the stereoselectivity in olefin polymerization-Reference-Cited by-同舟云学术

“C–H⋯π Interaction” regulates the stereoselectivity in olefin polymerization

Published:2019 Issue:47 Volume:55 Page:6689-6692
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhao Yanan¹²³⁴⁵^ORCID,Luo Gen¹²³⁴⁵^ORCID,Kang Xiaohui¹²³⁴⁵^ORCID,Guo Fang¹²³⁴⁵^ORCID,Zhu Xuefeng⁶³⁴⁵,Zheng Rencheng⁶³⁴⁵,Hou Zhaomin⁷⁸⁹¹⁰^ORCID,Luo Yi¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals

2. School of Chemical Engineering

3. Dalian University of Technology

4. Dalian 116024

5. China

6. School of Automotive Engineering

7. Organometallic Chemistry Laboratory, RIKEN Cluster for Pioneering Research, and Advanced Catalysis Research Group

8. RIKEN Center for Sustainable Resource Science

9. Wako

10. Japan

Abstract

DFT calculations reveal that a coordinating THF plays an essential role in regulating the stereoselectivity via C–H⋯π noncovalent interaction.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

State Key Laboratory of Automotive Safety and Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC02165E

Reference26 articles.

1. Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls

2. Half-Sandwich Rare-Earth-Catalyzed Olefin Polymerization, Carbometalation, and Hydroarylation

3. Precisely Controlled Polymerization of Styrene and Conjugated Dienes by Group 3 Single-Site Catalysts

4. Substitution Effects in Highly Syndioselective Styrene Polymerization Catalysts Based on Single-Component Allyl ansa-Lanthanidocenes: An Experimental and Theoretical Study

5. On the Initiation Mechanism of Syndiospecific Styrene Polymerization Catalyzed by Single-Componentansa-Lanthanidocenes

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