The mechanistic investigations of photochemical carbonyl elimination and oxidative addition reactions of (η5-C5H5)M(CO)3, (M = Mn and Re) complexes-Reference-Cited by-同舟云学术

The mechanistic investigations of photochemical carbonyl elimination and oxidative addition reactions of (η5-C5H5)M(CO)3, (M = Mn and Re) complexes

Published:2018 Issue:20 Volume:8 Page:10987-10998
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Zhang Zheng-Feng¹²³⁴,Su Ming-Der¹²³⁴⁵^ORCID

Affiliation:

1. Department of Applied Chemistry

2. National Chiayi University

3. Chiayi 60004

4. Taiwan

5. Department of Medicinal and Applied Chemistry

Abstract

The theoretical works suggest that under UV photoirradiation, η⁵-CpMn(CO)₃ follows either the conical intersection mechanism or the intersystem crossing mechanism to obtain the final oxidative addition product. However, η⁵-CpRe(CO)₃ proceeds only the singlet state channel.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA01118D

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